Mix and (Mis)match: further studies of the electronic structure and mixed-valence characteristics of 1,4-diethynylbenzene-bridged bimetallic complexes
Author:
Affiliation:
1. School of Molecular Sciences
2. University of Western Australia
3. Crawley
4. Australia
Abstract
Infra-red spectroelectrochemical studies of [{Cp′(CO)xM′}(μ-CCC6H4CC){M(PP)Cp′}]n+ [n = 0, 1] illustrate limited ground-state interactions in these donor–acceptor compounds and the localised nature of the one-electron redox processes.
Funder
Australian Research Council
University of Western Australia
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01794A
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