Electron transfer mediates vibrational relaxation of CO in collisions with Ag(111)
Author:
Affiliation:
1. Institute for Physical Chemistry, University of Goettingen
2. 37077 Goettingen
3. Germany
4. Department of Dynamics at Surfaces, Max-Planck-Institute for Biophysical Chemistry
Abstract
We report vibrational relaxation probabilities for CO(v = 17) scattered from Ag(111) and compare our results to studies on other molecule–surface systems, which indicates a clear dependence of the relaxation probability on the work function of the surface and the electron binding energy of the molecule.
Funder
Deutsche Forschungsgemeinschaft
Alexander von Humboldt-Stiftung
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP06041J
Reference36 articles.
1. Observation of Direct Vibrational Excitation in Gas-Surface Collisions: NO on Ag(111)
2. Zur Quantentheorie der Molekeln
3. Multiquantum Vibrational Excitation of NO Scattered from Au(111): Quantitative Comparison of Benchmark Data to Ab Initio Theories of Nonadiabatic Molecule-Surface Interactions
4. Observation of orientation-dependent electron transfer in molecule-surface collisions
5. State-to-State Time-of-Flight Measurements of NO Scattering from Au(111): Direct Observation of Translation-to-Vibration Coupling in Electronically Nonadiabatic Energy Transfer
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