Combined experimental and computational study of the photoabsorption of the monodoped and nondoped nanoclusters Au24Pt(SR)18, Ag24Pt(SR)18, and Ag25(SR)18

Author:

D’Antoni Pierpaolo1,Sementa Luca2,Bonacchi Sara3ORCID,Reato Mattia3ORCID,Maran Flavio34ORCID,Fortunelli Alessandro2ORCID,Stener Mauro1ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Trieste, Via Giorgieri 1, I-34127 Trieste, Italy

2. CNR-ICCOM & IPCF, Consiglio Nazionale delle Ricerche, Via Giuseppe Moruzzi 1, I-56124 Pisa, Italy

3. Department of Chemistry, University of Padova, Via Marzolo 1, I-35131 Padova, Italy

4. Department of Chemistry, University of Connecticut, 55 North Eagleville Road, Storrs, Connecticut 06269, USA

Abstract

The photoabsorption spectra of a set of monolayer-protected clusters and nanoalloys have been obtained at low temperature and compared with accurate TDDFT calculations. An excellent match between theory and experiment was obtained.

Funder

European Cooperation in Science and Technology

Ministero dell'Istruzione e del Merito

Dipartimento di Scienze Chimiche, Università degli Studi di Padova

Università degli Studi di Trieste

Beneficentia Stiftung

Publisher

Royal Society of Chemistry (RSC)

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