On-column internal standardisation as an alternative calibration strategy for speciation analysis: feasibility demonstration through analysis of inorganic As in rice

Author:

Petrov Panayot1ORCID,Cowen Simon1,Goenaga-Infante Heidi1ORCID

Affiliation:

1. LGC Ltd, National Measurement Laboratory, Queens Road, Teddington, TW11 0LY, UK

Abstract

On-column species-specific internal calibration, based on the injection of internal standard, which is the same as the analyte species, compensates for on-column losses, signal drift and others, and provides accurate measurements with low uncertainty.

Funder

Department for Business, Energy and Industrial Strategy, UK Government

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Chemical Engineering,Analytical Chemistry

Reference18 articles.

1. J. P.Vicente , J. E.Romero and S. C.Broch , Validation of Analytical Methods Based on Chromatographic Techniques: An Overview , in Analytical Separation Science , Wiley-VCH Verlag GmbH & Co. KGaA , 1st edn, 2015 , vol. 14 , pp. 1–52

2. B.Magnusson and U.Örnemark , EURACHEM Guide: The Fitness for Purpose of Analytical Methods: A Laboratory Guide to Method Validation and Related Topics, issued in , 1998

3. Standard additions: myth and reality

4. Using calibration approaches to compensate for remaining matrix effects in quantitative liquid chromatography/electrospray ionization multistage mass spectrometric analysis of phytoestrogens in aqueous environmental samples

5. Standard addition with internal standardisation as an alternative to using stable isotope labelled internal standards to correct for matrix effects—Comparison and validation using liquid chromatography-​tandem mass spectrometric assay of vitamin D

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3