Using molecular straps to engineer conjugated porous polymer growth, chemical doping, and conductivity-Reference-Cited by-同舟云学术

Using molecular straps to engineer conjugated porous polymer growth, chemical doping, and conductivity

Published:2023 Issue:20 Volume:14 Page:5510-5518
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mohanan Manikandan¹²,Ahmad Humayun³,Ajayan Pooja⁴,Pandey Prashant K.¹,Calvert Benjamin M.¹²,Zhang Xinran²⁵,Chen Fu⁶,Kim Sung J.⁷^ORCID,Kundu Santanu³^ORCID,Gavvalapalli Nagarjuna¹²^ORCID

Affiliation:

1. Department of Chemistry, Georgetown University, Washington, D.C., USA

2. Institute for Soft Matter Synthesis and Metrology, Georgetown University, Washington, D.C., USA

3. Department of Physics, Georgetown University, Washington, D.C., USA

4. Dave C. Swalm School of Chemical Engineering, Mississippi State University, Mississippi, USA

5. Department of Chemistry, University of California, Riverside, California, USA

6. Department of Chemistry, University of Maryland, College Park, Maryland, USA

7. Department of Chemistry, Howard University, Washington D.C., USA

Abstract

We show that the π-face strapped repeat units, unlike conventional monomers, help to overcome the strong interchain interactions, extend network residence time, tune network growth, and increase chemical doping and conductivity in 3D-conjugated porous polymers.

Funder

National Science Foundation

Georgetown University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00983A

Reference59 articles.

1. Advances in Conjugated Microporous Polymers

2. Conjugated porous polymers: incredibly versatile materials with far-reaching applications