The reactions of TiCl3, and of UF4with TiCl3in liquid ammonia: unusual coordination spheres in [Ti(NH3)8]Cl3·6NH3and [UF(NH3)8]Cl3·3.5NH3-Reference-Cited by-同舟云学术

The reactions of TiCl3, and of UF4with TiCl3in liquid ammonia: unusual coordination spheres in [Ti(NH3)8]Cl3·6NH3and [UF(NH3)8]Cl3·3.5NH3

Published:2015 Issue:59 Volume:51 Page:11826-11829
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Woidy Patrick¹²³,Karttunen Antti J.⁴⁵⁶⁷,Rudel Stefan S.¹²³,Kraus Florian¹²³

Affiliation:

1. Anorganische und Fluorchemie der Philipps-Universität Marburg

2. 35032 Marburg

3. Germany

4. Department of Chemistry

5. Aalto University

6. FI-00076 Aalto

7. Finland

Abstract

TiCl₃and NH₃form octaammine titanium(iii) chloride ammonia (1/6), [Ti(NH₃)₈]Cl₃·6NH₃, which is the first structurally characterized octaammine complex of a transition metal.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04411A

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