The reactions of TiCl3, and of UF4with TiCl3in liquid ammonia: unusual coordination spheres in [Ti(NH3)8]Cl3·6NH3and [UF(NH3)8]Cl3·3.5NH3

Author:

Woidy Patrick123,Karttunen Antti J.4567,Rudel Stefan S.123,Kraus Florian123

Affiliation:

1. Anorganische und Fluorchemie der Philipps-Universität Marburg

2. 35032 Marburg

3. Germany

4. Department of Chemistry

5. Aalto University

6. FI-00076 Aalto

7. Finland

Abstract

TiCl3and NH3form octaammine titanium(iii) chloride ammonia (1/6), [Ti(NH3)8]Cl3·6NH3, which is the first structurally characterized octaammine complex of a transition metal.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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5. V. Doetsch , J.Jander, U.Engelhardt, C.Lafrenz, J.Fischer, H.Nagel, W.Renz, G.Türk, T.von Volkmann and G.Weber, Chemistry in Nonaqueous Ionizing Solvents – Volume I Chemistry in Anhydrous Liquid Ammonia – Part 1 Anorganische Und Allgemeine Chemie in Flüssigem Ammoniak, Friedr. Vieweg & Sohn, Braunschweig, 1966

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