Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives via photochemical cycloaddition of dialkylsilylene-Reference-Cited by-同舟云学术

Transformation of azulenes to bicyclic [4]dendralene and heptafulvene derivatives via photochemical cycloaddition of dialkylsilylene

Published:2015 Issue:53 Volume:51 Page:10707-10709
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kosai Tomoyuki¹²³⁴⁵,Ishida Shintaro¹²³⁴⁵,Iwamoto Takeaki¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Tohoku University

4. Sendai 980-8578

5. Japan

Abstract

Regioselective cycloaddition of dialkylsilylene upon irradiation converts azulene and guaiazulene to bicyclic [4]dendralene and heptafulvene derivatives, respectively.

Funder

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science, and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC03424H

Reference29 articles.

1. Stable Heavier Carbene Analogues

2. N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands

3. Development of Reactions of Silacyclopropanes as New Methods for Stereoselective Organic Synthesis

4. A Novel Reactivity of a Silylene: The First Examples of [1 + 2] Cycloaddition with Aromatic Compounds

5. Excited-State Reactions of an Isolable Silylene with Aromatic Compounds

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