Structural investigation of Na3NpO4 and Na3PuO4 using X-ray diffraction and 237Np Mössbauer spectroscopy-Reference-Cited by-同舟云学术

Structural investigation of Na3NpO4 and Na3PuO4 using X-ray diffraction and 237Np Mössbauer spectroscopy

Published:2015 Issue:42 Volume:44 Page:18370-18377
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Smith A. L.¹²³⁴⁵,Raison P. E.¹²³⁴⁵,Hen A.¹²³⁴⁵,Bykov D.¹²³⁴⁵,Colineau E.¹²³⁴⁵,Sanchez J.-P.⁶⁷⁸⁹¹⁰,Konings R. J. M.¹²³⁴⁵,Cheetham A. K.¹¹¹²¹³¹⁴

Affiliation:

1. European Commission

2. Joint Research Centre

3. Institute for Transuranium Elements

4. D-76125 Karlsruhe

5. Germany

6. CEA

7. INAC-SPSMS

8. Grenoble

9. France

10. Université de Grenoble Alpes

11. Department of Materials Science and Metallurgy

12. University of Cambridge

13. Cambridge

14. UK

Abstract

The crystal structures of Na₃NpO₄ and Na₃PuO₄ have been solved for the first time ab initio, and the pentavalence of the neptunium cation has been confirmed using Mössbauer spectroscopy.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02168E

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