Group 2 metal bis(arenecarbochalcogenoate)(crown ether) complexes: isolation and structural analysis

Author:

Tatematsu Yoshiharu12345,Kato Shinzi12345ORCID,Nakata Norio12345ORCID,Ebihara Masahiro12345,Niyomura Osamu67895,Sugamata Koh11011125ORCID,Yukimoto Mariko11011125,Minoura Mao11011125

Affiliation:

1. Department of Chemistry

2. Faculty of Engineering

3. Gifu University

4. Gifu 501-1193

5. Japan

6. Department of Applied Chemistry

7. College of Engineering

8. Chubu University

9. Kasugai 487-8501

10. College of Science

11. Rikkyo University

12. Tokyo 171-8501

Abstract

A series of Group 2 metal bis(arenecarbochalcogenoato)(crown ether) complexes were synthesized and their structures were revealed by X-ray analyses.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference62 articles.

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2. S. B. Elliott , in The Alkaline-earth and Heavy-metal Soaps , Reinhold Publishing Co. , New York , 1946

3. Carbonyl sulfide insertion reactions into metal-alkoxide bonds. Synthesis and molecular structure of di[bis(methylthiocarbonato)tris (methanol)calcium]

4. Insertion of COS into Group 2 metal–ethoxide bonds; crystal structures of [Mg(OCSOEt)2(EtOH)4] and [Sr3(OCSOEt)6(EtOH)8]

5. Syntheses and Structure Determinations of Calcium Thiolates

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