Aromatic Pummerer reaction for the remote para- or ortho-benzyl nucleophilic functionalization-Reference-Cited by-同舟云学术

Aromatic Pummerer reaction for the remote para- or ortho-benzyl nucleophilic functionalization

Published:2018 Issue:6 Volume:5 Page:1019-1021
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Bao Xingping¹²³⁴⁵,Xu Guangyu⁶⁷⁸⁹⁵,Yao Jinzhong¹²³⁴⁵,Zhou Hongwei¹²³⁴⁵^ORCID

Affiliation:

1. College of Biological

2. Chemical Sciences and Engineering

3. Jiaxing University

4. Jiaxing 314001

5. People's Republic of China

6. Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education)

7. College of Chemistry and Chemical Engineering

8. Hunan Normal University

9. Changsha 410081

Abstract

The classic Pummerer reaction involves an α-substituted sulfide via an elimination/addition of a thionium ion. In this paper, we reported a remote para- or ortho-benzyl nucleophilic functionalization using an aromatic Pummerer process. A plausible mechanism involving a quinone thionium intermediate was proposed to explain this reaction.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C7QO00970D

Reference34 articles.

1. Cascades of Interrupted Pummerer Reaction-Sigmatropic Rearrangement

2. Fluoro-Pummerer rearrangement and analogous reactions

3. Beyond the Pummerer Reaction: Recent Developments in Thionium Ion Chemistry