A series of nickel(ii) thiocyanate complexes comprising various molar contents of isonicotinamide and water as ligands or co-crystallized moieties – an experimental and computational study

Author:

Hok Lucija1ORCID,Vianello Robert1ORCID,Matković-Čalogović Dubravka2ORCID,Karanović Ljiljana3ORCID,Roca Sunčica1ORCID,Jaźwiński Jarosław4ORCID,Tašner Marina2,Vušak Darko2,Đaković Marijana2ORCID,Popović Zora2ORCID

Affiliation:

1. Ruđer Bošković Institute, Zagreb, Croatia

2. Department of Chemistry, Faculty of Science, University of Zagreb, Zagreb, Croatia

3. Laboratory for Crystallography, Faculty of Mining and Geology, University of Belgrade, Belgrade, Serbia

4. Institute of Organic Chemistry, Polish Academy of Sciences, Warsaw, Poland

Abstract

Crystal screening by varying isonicotinamide content added to Ni(ii) thiocyanate in water led to seven nickel complexes, whose structure and altered stoichiometries were analyzed by X-ray diffraction, NMR and IR spectroscopies, and DFT calculations.

Funder

Hrvatska Zaklada za Znanost

Sveučilište u Zagrebu

Ministry of Science and Technology, Croatia

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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