Metal−organic framework encapsulated Pd nanoparticles: towards advanced heterogeneous catalysts
Author:
Affiliation:
1. School of Chemistry and Chemical Engineering
2. South China University of Technology
3. Guangzhou 510640, China
4. Departamento de Química Orgánica
5. Universidad de Córdoba
6. Córdoba, Spain
Abstract
Palladium precursors were encapsulated through ligand design prior to the MOF assembly, achieving uniformly distributed Pd NPs inside the cavities of MOFs. The embedded Pd NPs exhibited significantly improved catalytic efficiencies as compared to those synthesized by traditional impregnation method, due to the nano-confinement and electron-donation effects offered by MOFs.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC01847H
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