Competition and cooperativity of hydrogen-bonding and tetrel-bonding interactions involving triethylene diamine (DABCO), H2O and CO2in air

Author:

Yang Jianming123,Yu Qinwei123,Yang Fang-Ling45673,Lu Ka45673,Yan Chao-Xian45673,Dou Wei45673,Yang Lizi45673ORCID,Zhou Pan-Pan45673ORCID

Affiliation:

1. Xi’an Modern Chemistry Research Institute

2. Xi’an 710065

3. P. R. China

4. Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province

5. College of Chemistry and Chemical Engineering

6. Lanzhou University

7. Lanzhou

Abstract

Triethylene diamine (DABCO) can interact with H2O and CO2in air to form dimeric and trimeric complexesviahydrogen bond, tetrel bond as well as van der Waals interactions.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference57 articles.

1. G. R. Desiraju and T.Steiner , The Weak Hydrogen Bond , Oxford University Press , Oxford , 1999

2. G. A. Jeffrey , An Introduction to Hydrogen Bonding , Oxford University Press , New York , 1997

3. E. S. Kryachko , Hydrogen Bonding-New Insights , Springer , Dordrecht, The Netherlands , 2006

4. S. Scheiner , Hydrogen Bonding , Oxford University Press , New York , 1997

5. Tetrel-Bonding Interaction: Rediscovered Supramolecular Force?

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