Spiro-based diamond-type nanogrids (DGs) via two ways: ‘A1B1’/‘A2 + B2’ type gridization of vertical spiro-based fluorenol synthons

Author:

Wei Ying1ORCID,Li Yang1,Lin Dongqing1,Jin Dong1,Du Xue1,Zhong Chunxiao1,Zhou Ping1,Sun Yue1,Xie Linghai1ORCID,Huang Wei12ORCID

Affiliation:

1. Centre for Molecular Systems and Organic Devices (CMSOD), State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China

2. Frontiers Science Center for Flexible Electronics (FSCFE), MIIT Key Laboratory of Flexible Electronics (KLoFE), Northwestern Polytechnical University, Xi'an 710072, China

Abstract

Diamond-type nanogrids (DGs), can helically expand to form spiro-linked polymers. Herein, we designed and synthesized two types of DGs, DGs-1 (A1B1 mode) in 44–50% yields, and DGs-2 (A2 + B2 mode) in 64% yield.

Funder

National Natural Science Foundation of China

State Key Laboratory of Supramolecular Structure and Materials

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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