Development of a Ni-promoted, selective electrochemical reductive cleavage of the C–O bond in lignin model compound benzyl phenyl ether-Reference-Cited by-同舟云学术

Development of a Ni-promoted, selective electrochemical reductive cleavage of the C–O bond in lignin model compound benzyl phenyl ether

Published:2022 Issue:16 Volume:24 Page:6295-6305
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Lin Fang¹²,TSE Ho-Yin²³^ORCID,Erythropel Hanno C.²⁴⁵^ORCID,Petrović Predrag V.²⁵^ORCID,Garedew Mahlet²^ORCID,Chen Jinshan²,Lam Jason Chun-Ho⁶^ORCID,Anastas Paul T.¹²⁴⁵⁷^ORCID

Affiliation:

1. Department of Chemistry, Yale University, 225 Prospect St, New Haven, CT, USA

2. Center for Green Chemistry & Green Engineering at Yale, 370 Prospect St, New Haven, CT, USA

3. Department of Civil & Environmental Engineering, The Hong Kong Polytechnic University, Hong Kong

4. Department of Chemicals and Environmental Engineering, Yale University, 17 Hillhouse Ave, New Haven, CT, USA

5. Yale School of the Environment, 195 Prospect St, New Haven, CT, USA

6. City University of Hong Kong, School of Energy and Environment, Kowloon Tong, Hong Kong

7. Yale School of Public Health, 60 College St, New Haven, CT, USA

Abstract

Ni-promoted, highly selective electrochemical protocol to reductively cleave the benzylic C–O bond of the α-O-4 lignin model compound benzyl phenyl ether (BPE) at room temperature and ambient pressure.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D2GC01510B

Reference57 articles.

1. Lignin Valorization: Improving Lignin Processing in the Biorefinery

2. Lignin-first biomass fractionation: the advent of active stabilisation strategies

3. From Lignin to Chemicals: Hydrogenation of Lignin Models and Mechanistic Insights into Hydrodeoxygenation via Low-Temperature C–O Bond Cleavage

4. Catalytic Lignin Depolymerization to Aromatic Chemicals

5. “Waste to Wealth”: Lignin as a Renewable Building Block for Energy Harvesting/Storage and Environmental Remediation

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