A dodecanuclear copper(ii) cage self-assembled from six dicopper building units

Author:

Ghosh Aloke Kumar123,Pait Moumita123,Clérac Rodolphe45678,Mathonière Corine491078,Bertolasi Valerio11121314,Bauzá Antonio151617,Frontera Antonio151617,Pramanik Kausikisankar1811920,Ray Debashis123

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology

3. Kharagpur 721 302, India

4. CNRS

5. CRPP

6. UPR 8641

7. F-33600 Pessac, France

8. Univ. Bordeaux

9. ICMCB

10. UPR 9048

11. Dipartimento di Scienze Chimiche e Farmaceutiche

12. Centro di Strutturistica Diffrattometica

13. Università di Ferrara

14. 44121 Ferrara, Italy

15. Departament de Química

16. Universitat de les Illes Balears

17. Palma, Spain

18. Inorganic Chemistry Section

19. Jadavpur University

20. Kolkata-70032, India

Abstract

Sandwich capping of two {Cu33-NO3)}5− triangles over a hydroxido-bridged {Cu6} hexagon, supported by six ligands resulted in a novel Cu12 cage in a flattened cuboctahedral topology.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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