Functionalisation of esters via 1,3-chelation using NaOtBu: mechanistic investigations and synthetic applications
Author:
Affiliation:
1. Department of Energy Science
2. Sungkyunkwan University
3. Suwon 16419
4. Republic of Korea
5. Department of Chemistry
6. Hankuk University of Foreign Studies
7. Yongin 17035
Abstract
Unusual nucleophilic behavior of a metal t-butoxide in a transesterification reaction was demonstrated by NMR and real-time IR spectroscopies and deuterium-labeling experiments.
Funder
National Research Foundation of Korea
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/QO/D0QO01135E
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