Palladium-catalyzed decarboxylative gem-selective addition of alkynoic acids to terminal alkynes
Author:
Affiliation:
1. Department of Chemistry
2. Chonnam National University
3. Gwangju 61186
4. Republic of Korea
5. Materials Research Team
6. Display Research Center
7. Samsung Display Co.
8. Ltd.
9. Gyeonggi-do 17113
Abstract
Alkynoic acids added to terminal alkynes to give gem-1,3-enynes with high selectivity and good yields. In addition, the reaction of alkynoic acids with propiolic acid provided the corresponding gem-1,3-enynes via double decarboxylation.
Funder
National Research Foundation of Korea
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO01133A
Reference64 articles.
1. Transition metal-catalyzed decarboxylative cross-coupling reactions
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3. Recent advances of propiolic acids in organic reactions
4. Synthesis of aryl alkynyl carboxylic acids and aryl alkynes from propiolic acid and aryl halides by site selective coupling and decarboxylation
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