Stereoselective aldol reactions using pseudo C2 symmetric 1-benzyl-4-(trifluoromethyl)piperidine-2,6-dione-Reference-Cited by-同舟云学术

Stereoselective aldol reactions using pseudo C2 symmetric 1-benzyl-4-(trifluoromethyl)piperidine-2,6-dione

Published:2018 Issue:71 Volume:54 Page:9913-9916
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Inoue Yuta¹²³⁴⁵,Hatayama Takahiro¹²³⁴⁵,Kawasaki-Takasuka Tomoko¹²³⁴⁵,Agou Tomohiro⁶⁷⁸⁵^ORCID,Kubota Toshio⁶⁷⁸⁵^ORCID,Yamazaki Takashi¹²³⁴⁵^ORCID

Affiliation:

1. Division of Applied Chemistry

2. Institute of Engineering

3. Tokyo University of Agriculture and Technology

4. Koganei 184-8588

5. Japan

6. Department of Biomolecular Functional Engineering

7. Ibaraki University

8. Hitachi 316-8511

Abstract

Crossed aldol reactions of the CF₃-containing pseudo C₂ symmetric cyclic imide 3 were performed by way of the corresponding lithium and boron bisenolates to stereoselectively furnish the desired products 4.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC05458D

Reference27 articles.

1. Stereoselective Aldol Reaction of Glutarimides Using Pseudo C2 Symmetry

2. Highly Stereoselective TiCl4-Catalyzed Evans−Aldol and Et3Al-Mediated Reformatsky Reactions. Efficient Accesses to Optically Active syn- or anti-α-Trifluoromethyl-β-hydroxy Carboxylic Acid Derivatives

3. Highly Diastereoselective Aldol Reaction with α-CF3-Substituted Enolates

4. Reversal of Diastereoselectivity in Reactions of the Trifluoroacetaldehyde Ethyl Hemiacetal with Enamines and Imines: Metal-Free, Complementary anti- and syn-Selective Synthesis of 4,4,4-Trifluoro-1-aryl-3-hydroxy-2-methyl-1-butanones

5. Organocatalytic Asymmetric Direct Aldol Reactions of Trifluoroacetaldehyde Ethyl Hemiacetal with Aromatic Methyl Ketones

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