Catalyst control of selectivity in the C–O bond alumination of biomass derived furans
Author:
Affiliation:
1. Department of Chemistry
2. Molecular Sciences Research Hub
3. Imperial College London
4. London
5. UK
6. BioISI – Biosystems & Integrative Sciences Institute
7. Faculty of Sciences
8. University of Lisboa
9. 1749-016 Lisboa
10. Portugal
Abstract
Non-catalysed and catalysed reactions of aluminium reagents with furans, dihydrofurans and dihydropyrans were investigated and lead to ring-expanded products due to the insertion of the aluminium reagent into a C–O bond of the heterocycle.
Funder
H2020 European Research Council
H2020 Marie Skłodowska-Curie Actions
Royal Society
“la Caixa” Foundation
Fundação para a Ciência e a Tecnologia
European Regional Development Fund
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC01918F
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