Low band gap semiconducting covalent organic framework films with enhanced photocatalytic hydrogen evolution

Author:

Ghosh Samrat123ORCID,Küçükkeçeci Hüseyin3ORCID,Paitandi Rajendra Prasad4ORCID,Weigelt Vincent3ORCID,Dippold Veit3ORCID,Seki Shu4ORCID,Thomas Arne3ORCID

Affiliation:

1. Inorganic and Physical Chemistry Laboratory, Council of Scientific and Industrial Research (CSIR), Central Leather Research Institute (CLRI), Chennai – 600020, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad – 201002, India

3. Department of Chemistry/Functional Materials, Technische Universität Berlin, Berlin 10623, Germany

4. Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

A contrasting photocatalytic mechanism was observed for semiconducting covalent organic frameworks (COFs). J-type aggregation favors exciton migration in the powder state, while charge transport governs the photocatalytic activity in the films.

Funder

Alexander von Humboldt-Stiftung

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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