Transition metal-free reductive coupling of allylic sulfonylhydrazones with aryl boronic acids for C(sp<sup>3</sup>)–C(sp<sup>2</sup>) bond formation-Reference-Cited by-同舟云学术

Transition metal-free reductive coupling of allylic sulfonylhydrazones with aryl boronic acids for C(sp³)–C(sp²) bond formation

Published:2022 Issue:44 Volume:20 Page:8672-8684
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Ali Kasim¹²,Prajapati Gurudayal³,Ampapathi Ravi Sankar³²,Panda Gautam¹²^ORCID

Affiliation:

1. Medicinal & Process Chemistry Division, CSIR-Central Drug Research Institute, Lucknow 226031, India

2. Academy of Scientific & Industrial Research (AcSIR), Ghaziabad, Uttar Pradesh-201002, India

3. NMR Centre, SAIF, CSIR-Central Drug Research Institute, Lucknow 226031, India

Abstract

The reductive coupling between allylic sulfonylhydrazones and aryl boronic acids gives 1,3-diarylpropene systems with good to excellent yields under very simple reaction conditions without metal catalysts and an inert atmosphere.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

University Grants Commission

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01472F

Reference43 articles.

1. Metal-free carbon–carbon bond-forming reductive coupling between boronic acids and tosylhydrazones

2. Olefination of Carbonyl Compounds through Reductive Coupling of Alkenylboronic Acids and Tosylhydrazones

3. Stereoselective Csp3-Csp2Bond-Forming Reactions by Transition-Metal-Free Reductive Coupling of Cyclic Tosylhydrazones with Boronic Acids

4. Switchable 2,2,2-Trifluoroethylation andgem-Difluorovinylation of Organoboronic Acids with 2,2,2-Trifluorodiazoethane

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