Mechanistic insights into the formation of oxenium ions and radical intermediates through the photolysis of phenylhydroxylamine and its derivatives-Reference-Cited by-同舟云学术

Mechanistic insights into the formation of oxenium ions and radical intermediates through the photolysis of phenylhydroxylamine and its derivatives

Published:2018 Issue:4 Volume:20 Page:2220-2229
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Yang Yumei¹²³^ORCID,Fang Weihai¹²³,Chen Xuebo¹²³^ORCID

Affiliation:

1. Key Laboratory of Theoretical and Computational Photochemistry of Ministry of Education, Department of Chemistry, Beijing Normal University

2. Beijing 100875

3. P. R. China

Abstract

The electronic structures and related properties, as well as reactivities, of generated oxenium ions and radicals are analyzed by calculating the minimum energy profiles of the photolysis of different precursors.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP07071C

Reference70 articles.

1. Characterization of Reactive Intermediates Generated During Photolysis of 4-Acetoxy-4-aryl-2,5-cyclohexadienones: Oxenium Ions and Aryloxy Radicals

2. Comparison of Phenylcarbene and Phenylnitrene

3. Remarkable catalysis of intersystem crossing of singlet (pentafluorophenyl)nitrene

4. Intermolecular reaction of an aryl nitrene

5. Formation of metal ion-nitrene complexes

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