A remarkably strained cyclopyrenylene trimer that undergoes metal-free direct oxygen insertion into the biaryl C

A remarkably strained cyclopyrenylene trimer that undergoes metal-free direct oxygen insertion into the biaryl C–C σ-bond

Published:2019 Issue:28 Volume:10 Page:6785-6790
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kurosaki Ryo¹²³⁴^ORCID,Hayashi Hironobu¹²³⁴^ORCID,Suzuki Mitsuharu⁵⁶⁷⁸⁹^ORCID,Jiang Julong¹⁰¹¹¹²³⁴,Hatanaka Miho¹²³⁴¹⁰^ORCID,Aratani Naoki¹²³⁴^ORCID,Yamada Hiroko¹²³⁴^ORCID

Affiliation:

1. Division of Materials Science

2. Nara Institute of Science and Technology (NAIST)

3. Nara 630-0192

4. Japan

5. Department of Material and Life Science

6. Division of Advanced Science and Biotechnology

7. Graduate School of Engineering

8. Osaka University

9. Suita

10. Institute for Research Initiatives

11. Division for Research Strategy

12. NAIST

Abstract

A remarkably strained cyclopyrenylene trimer was synthesized and it underwent the first biaryl C–C σ-bond cleavage with ¹O₂.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01777A

Reference48 articles.

1. Exploration of Nano-Saturns: A Spectacular Sphere-Ring Supramolecular System

2. Multifunctional π-expanded oligothiophene macrocycles

3. Fluorenyl Based Macrocyclic Polyradicaloids

4. Bowls, Hoops, and Saddles: Synthetic Approaches to Curved Aromatic Molecules

5. Strain-Induced Double Carbon-Carbon Bond Activations of Cycloparaphenylenes by a Platinum Complex: Application to the Synthesis of Cyclic Diketones

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