Mono-oxo molybdenum(vi) and tungsten(vi) complexes bearing chelating aryloxides: synthesis, structure and ring opening polymerization of cyclic esters

Author:

Sun Ziyue1234,Zhao Yanxia1234,Prior Timothy J.5678ORCID,Elsegood Mark R. J.910118ORCID,Wang Kuiyuan5678,Xing Tian5678,Redshaw Carl12345ORCID

Affiliation:

1. College of Chemistry and Material Science

2. Northwest University

3. 710069 Xi'an

4. China

5. Department of Chemistry

6. The University of Hull

7. Hull

8. UK

9. Chemistry Department

10. Loughborough University

11. Leicestershire

Abstract

Mono-oxo Mo and W complexes bearing di- or tetra-phenolates were active for the ROP of small cyclic esters, albeit with poor control. Related metallocalix[4]arenes were less active.

Funder

Northwest University

China Scholarship Council

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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