Mono-oxo molybdenum(vi) and tungsten(vi) complexes bearing chelating aryloxides: synthesis, structure and ring opening polymerization of cyclic esters
Author:
Affiliation:
1. College of Chemistry and Material Science
2. Northwest University
3. 710069 Xi'an
4. China
5. Department of Chemistry
6. The University of Hull
7. Hull
8. UK
9. Chemistry Department
10. Loughborough University
11. Leicestershire
Abstract
Mono-oxo Mo and W complexes bearing di- or tetra-phenolates were active for the ROP of small cyclic esters, albeit with poor control. Related metallocalix[4]arenes were less active.
Funder
Northwest University
China Scholarship Council
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04566F
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3. The biologically relevant oxygen atom transfer chemistry of molybdenum: from synthetic analogue systems to enzymes
4. Comparative molecular chemistry of molybdenum and tungsten and its relation to hydroxylase and oxotransferase enzymes
5. A mononuclear molybdenum(V) mono-oxo biphenyl-2,2′-dithiolate complex in which the metal resides within a cleft formed by the ligands and that exhibits N-H...S hydrogen bonding in the solid state
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