Tuning the photophysical properties of lanthanide(iii)/zinc(ii) ‘encapsulated sandwich’ metallacrowns emitting in the near-infrared range

Author:

Eliseeva Svetlana V.1ORCID,Nguyen Tu N.2ORCID,Kampf Jeff W.2,Trivedi Evan R.2ORCID,Pecoraro Vincent L.2ORCID,Petoud Stéphane1ORCID

Affiliation:

1. Centre de Biophysique Moléculaire, CNRS UPR 4301, F-45071 Orléans, Cedex 2, France

2. Department of Chemistry, Willard H. Dow Laboratories, University of Michigan, Ann Arbor, Michigan 48109, USA

Abstract

We have created a family of ‘encapsulated sandwich’ Zn16Ln(HA)16 metallacrowns and by detailed quantitative analysis demonstrated how the nature of the hydroximate ligand impacts photophysical properties of these complexes.

Funder

National Science Foundation

Ligue Contre le Cancer

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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