A highly active and chemoselective homobimetallic ruthenium catalyst for one-pot reductive amination in water

Author:

Deshmukh Gopal1ORCID,Rana Thakur Rochak Kumar1,Yadav Nikita1,Rajaraman Gopalan1ORCID,Murugavel Ramaswamy1ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India

Abstract

A bimetallic Ru(ii) complex efficiently catalyzes reductive amination of diverse substrates in water with the highest reported TONs and TOFs. Experimental and DFT calculations point to a cooperative effect for the increased efficiency at low catalyst loading (0.05 mol%).

Funder

Science and Engineering Research Board

CouncilofScientific and Industrial Research, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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