Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer-Reference-Cited by-同舟云学术

Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer

Published:2019 Issue:43 Volume:21 Page:23803-23807
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Pilz Frank Hendrik¹²³⁴⁵^ORCID,Lindner Jörg¹²³⁴⁵,Vöhringer Peter¹²³⁴⁵^ORCID

Affiliation:

1. Abteilung für Molekulare Physikalische Chemie

2. Institut für Physikalische und Theoretische Chemie

3. Rheinische Friedrich-Wilhelms-Universität

4. 53115 Bonn

5. Germany

Abstract

Step-scan FTIR-spectroscopy reveals the bimolecular reaction in the ferrioxalate photochemistry, which builds the molecular-level foundation of the Hatchard–Parker actinometer.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP05233J

Reference18 articles.

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2. A new sensitive chemical actinometer - II. Potassium ferrioxalate as a standard chemical actinometer

3. Photodecomposition of Complex Oxalates—Some Preliminary Experiments by Flash Photolysis

4. Electroanalytical measurements of flash-photolyzed ferrioxalate

5. Spectrophotometric and electrochemical studies of flash-photolyzed trioxalatoferrate(III)

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