Heterolytic cleavage of H2 by bifunctional manganese(i) complexes: impact of ligand dynamics, electrophilicity, and base positioning-Reference-Cited by-同舟云学术

Heterolytic cleavage of H2 by bifunctional manganese(i) complexes: impact of ligand dynamics, electrophilicity, and base positioning

Published:2014 Issue:12 Volume:5 Page:4729-4741
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Hulley Elliott B.¹²³⁴,Helm Monte L.¹²³⁴,Bullock R. Morris¹²³⁴

Affiliation:

1. Center for Molecular Electrocatalysis

2. Physical Sciences Division

3. Pacific Northwest National Laboratory

4. Richland, USA

Abstract

A balance of metal electrophilicity and ligand steric influences is required for facile, reversible H–H heterolytic cleavage in Mn complexes with pendant amines.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC01801J

Reference69 articles.

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5. Catalysis Without Precious Metals, ed. R. M. Bullock, Wiley-VCH, Weinheim, 2010

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