Rendering classical hydrophilic enantiopure Werner salts [M(en)3]n+nX−lipophilic (M/n= Cr/3, Co/3, Rh/3, Ir/3, Pt/4); new chiral hydrogen bond donor catalysts and enantioselectivities as a function of metal and charge-Reference-Cited by-同舟云学术

Rendering classical hydrophilic enantiopure Werner salts [M(en)3]n+nX−lipophilic (M/n= Cr/3, Co/3, Rh/3, Ir/3, Pt/4); new chiral hydrogen bond donor catalysts and enantioselectivities as a function of metal and charge

Published:2020 Issue:12 Volume:49 Page:3680-3691
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Maximuck William J.¹²³⁴^ORCID,Ganzmann Carola⁵⁶⁷,Alvi Scheherzad¹²³⁴^ORCID,Hooda Karan R.¹²³⁴,Gladysz John A.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Texas A&M University

3. College Station

4. USA

5. Institut für Organische Chemie and Interdisciplinary Center for Molecular Materials Friedrich-Alexander-Universität Erlangen-Nürnberg

6. 91054 Erlangen

7. Germany

Abstract

The halide anions of enantiopure hydrophilic Werner complexes are replaced by BAr_f⁻, providing lipophilic catalysts for enantioselective reactions.

Funder

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00523A

Reference90 articles.

1. Zur Kenntnis des asymmetrischen Kobaltatoms. I

2. Zur Kenntnis des asymmetrischen Kobaltatoms. II

3. Zur Kenntnis des asymmetrischen Kobaltatoms. III

4. Zur Kenntnis des asymmetrischen Kobaltatoms. IV

5. Zur Kenntnis des asymmetrischen Kobaltatoms. V

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