Mechanistic insight into oxygen atom transfer reactions by mononuclear manganese(iv)–oxo adducts
Author:
Affiliation:
1. The University of Kansas
2. Department of Chemistry and Center for Environmentally Beneficial Catalysis
3. Lawrence
4. USA
Abstract
Rate enhancements in sulfoxidation reactions are often associated with a change in mechanism. Kinetic studies of sulfoxidation reactions by a series of MnIV–oxo complexes reveal large rate changes while retaining an oxygen-atom transfer mechanism.
Funder
Basic Energy Sciences
National Institute of General Medical Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04436A
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