Mechanistic insight into oxygen atom transfer reactions by mononuclear manganese(iv)

Mechanistic insight into oxygen atom transfer reactions by mononuclear manganese(iv)–oxo adducts

Published:2021 Issue:10 Volume:50 Page:3577-3585
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Singh Priya¹²³⁴,Stewart-Jones Eleanor¹²³⁴,Denler Melissa C.¹²³⁴,Jackson Timothy A.¹²³⁴^ORCID

Affiliation:

1. The University of Kansas

2. Department of Chemistry and Center for Environmentally Beneficial Catalysis

3. Lawrence

4. USA

Abstract

Rate enhancements in sulfoxidation reactions are often associated with a change in mechanism. Kinetic studies of sulfoxidation reactions by a series of Mn^IV–oxo complexes reveal large rate changes while retaining an oxygen-atom transfer mechanism.

Funder

Basic Energy Sciences

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04436A

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