Ion-pairing in polyoxometalate chemistry: impact of fully hydrated alkali metal cations on properties of the keggin [PW12O40]3− anion
Author:
Affiliation:
1. Cherry L. Emerson Center for Scientific Computation
2. Emory University
3. Atlanta
4. USA
5. Department of Chemistry
Abstract
The [PW12O40]3−[M+(H2O)16]3 is a “hydrogen bonded” ion-pair complex for M = Li, Na and K, but is a “contact” ion-pair complex for M = Rb and Cs, intermolecular charge transfer from the solvated counter cations M+(H2O)16 to the anion [PW12O40]3−.
Funder
U.S. Department of Energy
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02239J
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