Synthesis of novel polyethers with abundant reactive sites and diverse skeletons based on the ring-opening reaction of D

Synthesis of novel polyethers with abundant reactive sites and diverse skeletons based on the ring-opening reaction of D–A cyclopropanes

Published:2020 Issue:37 Volume:11 Page:5969-5973
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Wu Shuai¹²³⁴⁵,Li Jun-Fang¹²³⁴⁵,Sun Xiu-Li¹²³⁴⁵^ORCID,Wang Xiao-Yan¹²³⁴⁵^ORCID,Tang Yong¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Organometallic Chemistry

2. Shanghai Institute of Organic Chemistry

3. Chinese Academy of Sciences

4. Shanghai 200032

5. China

Abstract

Based on the ring-opening reaction of D–A cyclopropanes, a facile synthesis of novel polyethers is developed with molecular weights up to 17.7 kg mol⁻¹.

Funder

Youth Innovation Promotion Association of the Chinese Academy of Sciences

National Natural Science Foundation of China

Chinese Academy of Sciences

National Basic Research Program of China

Science and Technology Commission of Shanghai Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2020/PY/D0PY01095B

Reference35 articles.

1. Functionalizable Stereocontrolled Cyclopolyethers by Ring-Closing Metathesis as Natural Polymer Mimics

2. Polycondensation as a Versatile Synthetic Route to Aliphatic Polycarbonates for Solid Polymer Electrolytes

3. Polyurethanes: Versatile Materials and Sustainable Problem Solvers for Today’s Challenges

4. High-Purity Discrete PEG-Oligomer Crystals Allow Structural Insight

5. Poly(ethylene glycol) in Drug Delivery: Pros and Cons as Well as Potential Alternatives

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