Gas-phase preparation of azulene (C10H8) and naphthalene (C10H8) via the reaction of the resonantly stabilized fulvenallenyl (C7H5˙) and propargyl (C3H3˙) radicals-Reference-Cited by-同舟云学术

Gas-phase preparation of azulene (C₁₀H₈) and naphthalene (C₁₀H₈) via the reaction of the resonantly stabilized fulvenallenyl (C₇H₅˙) and propargyl (C₃H₃˙) radicals

Published:2023 Issue:36 Volume:14 Page:9795-9805
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Wang¹,Yang Jiuzhong¹^ORCID,Zhao Long¹²^ORCID,Couch David³^ORCID,Marchi Myrsini San³,Hansen Nils³^ORCID,Morozov Alexander N.⁴,Mebel Alexander M.⁴^ORCID,Kaiser Ralf I.⁵^ORCID

Affiliation:

1. National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, China

2. School of Nuclear Science and Technology, University of Science and Technology of China, Hefei, Anhui 230027, China

3. Combustion Research Facility, Sandia National Laboratories, Livermore, CA 94551, USA

4. Department of Chemistry and Biochemistry, Florida International University, Miami, FL 33199, USA

5. Department of Chemistry, University of Hawaii at Manoa, Honolulu, HI 96822, USA

Abstract

The gas-phase reaction of two resonantly stabilized radicals synthesizes the 10π Hückel aromatic azulene and naphthalene – which can be embedded into saddle-shaped carbonaceous nanostructures exhibiting positive and negative curvatures.

Funder

National Natural Science Foundation of China

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03231K

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