Development of a multi-method analytical approach based on the combination of synchrotron radiation X-ray micro-analytical techniques and vibrational micro-spectroscopy methods to unveil the causes and mechanism of darkening of “fake-gilded” decorations in a Cimabue painting

Author:

Monico Letizia123ORCID,Prati Silvia4ORCID,Sciutto Giorgia4,Catelli Emilio4,Romani Aldo12,Balbas Diego Quintero4ORCID,Li Zelan4,De Meyer Steven3,Nuyts Gert3,Janssens Koen35,Cotte Marine67,Garrevoet Jan8,Falkenberg Gerald8,Tardillo Suarez Vanessa Isabel6,Tucoulou Remi6,Mazzeo Rocco4

Affiliation:

1. CNR-SCITEC, Via Elce di Sotto 8, I-06123 Perugia, Italy

2. SMAArt Centre, Department of Chemistry, Biology, and Biotechnology, University of Perugia, Via Elce di Sotto 8, I-06123 Perugia, Italy

3. AXIS Research Group, NANOlab Centre of Excellence, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium

4. Microchemistry and Microscopy Art Diagnostic Laboratory (M2ADL), Department of Chemistry “G. Ciamician”, University of Bologna – Ravenna Campus, Via G. Guaccimanni 42, I-48121 Ravenna, Italy

5. Rijksmuseum, Conservation & Restoration – Scientific Research, Hobbemastraat 22, 1071 ZC Amsterdam, Netherlands

6. ESRF, Avenue des Martyrs 71, F-38000 Grenoble, France

7. LAMS, CNRS UMR 8220, Sorbonne Université, UPMC Univ. Paris 06, Place Jussieu 4, F-75005 Paris, France

8. Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, D-22603 Hamburg, Germany

Abstract

Synchrotron radiation X-ray micro-analytical techniques and vibrational micro-spectroscopy methods were used to establish the factors and mechanism of darkening of “fake-gilded” decorations in the Maestà by Cimabue and aged paint mock-ups.

Funder

Università degli Studi di Perugia

H2020 Research Infrastructures

Horizon 2020 Framework Programme

European Synchrotron Radiation Facility

Deutsches Elektronen-Synchrotron

Fonds Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Spectroscopy,Analytical Chemistry

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