Regio- and stereoselective base-catalyzed assembly of 6-methylene-5-oxaspiro[2.4]heptanones from alkynyl cyclopropyl ketones-Reference-Cited by-同舟云学术

Regio- and stereoselective base-catalyzed assembly of 6-methylene-5-oxaspiro[2.4]heptanones from alkynyl cyclopropyl ketones

Published:2022 Issue:26 Volume:20 Page:5325-5333
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Samultceva Sofia O.¹,Dvorko Marina Yu.¹,Shabalin Dmitrii A.¹^ORCID,Ushakov Igor’ A.¹,Vashchenko Alexander V.¹,Schmidt Elena Yu.¹,Trofimov Boris A.¹^ORCID

Affiliation:

1. A.E. Favorsky Irkutsk Institute of Chemistry SB RAS, 1 Favorsky St, Irkutsk, 664033, Russian Federation

Abstract

A novel synthetic approach to almost unknown highly functionalized oxa-spirocyclopropanes from alkynyl cyclopropyl ketones is described.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB00854H

Reference42 articles.

1. Biosynthesis and Metabolism of Cyclopropane Rings in Natural Compounds

2. Cyclopropyl Scaffold: A Generalist for Marketed Drugs

3. Recent advances in the synthesis of cyclopropanes

4. Cyclopropanation Strategies in Recent Total Syntheses

5. Strategies for Construction of Cyclopropanes in Natural Products

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