Synthesis of new chiral Mn(iii)–salen complexes as recoverable and reusable homogeneous catalysts for the asymmetric epoxidation of styrenes and chromenes-Reference-Cited by-同舟云学术

Synthesis of new chiral Mn(iii)–salen complexes as recoverable and reusable homogeneous catalysts for the asymmetric epoxidation of styrenes and chromenes

Published:2022 Issue:3 Volume:46 Page:1308-1318
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Chaudhary Pooja¹,Yadav Geeta Devi¹,Damodaran Krishna K.²^ORCID,Singh Surendra¹^ORCID

Affiliation:

1. Department of Chemistry, University of Delhi, Delhi-110007, India

2. Department of Chemistry, University of Iceland, Reykjavik, Iceland

Abstract

New chiral Mn(iii)–salen complexes 1a–e and 2a–e were synthesized from the reaction of C2-symmetric chiral salen ligands and Mn(CH3COO)2·4H2O under an inert atmosphere followed by aerobic oxidation.

Funder

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D1NJ04758B

Reference46 articles.

1. W. J.De Klein , W. J.Mijs and C. R. I.De Jonge , Organic Synthesis by Oxidation with Metal Compounds , Plenum , New York , 1986 , pp. 261–314

2. Ruthenium-catalyzed epoxidation of unfunctionalized olefins with -butyl hydroperoxide

3. Metal-mediated enantioselective access to unfunctionalized aliphatic oxiranes: prochiral and chiral recognition