Influence of electronic vs. steric factors on the solid-state photochromic performances of new polyoxometalate/spirooxazine and spiropyran hybrid materials

Author:

Menet Clotilde12345,Serier-Brault Hélène12345,Oms Olivier67895,Dolbecq Anne67895,Marrot Jérôme67895,Saad Ali67895,Mialane Pierre67895,Jobic Stéphane12345,Deniard Philippe12345,Dessapt Rémi12345

Affiliation:

1. Institut des Matériaux Jean Rouxel

2. Université de Nantes

3. CNRS

4. 44322 Nantes cedex

5. France

6. Institut Lavoisier de Versailles

7. UMR 8180

8. Université de Versailles Saint-Quentin en Yvelines

9. 78035 Versailles cedex

Abstract

New supramolecular spirooxazine and spiropyran/polyoxotungstate materials have been designed. Their solid-state photochromic performances are strongly exalted compared to their isostructural Mo counterparts due to a more favorable electronic effect.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference59 articles.

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