Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: a convenient synthesis of Ni(ii)-thiolate complexes-Reference-Cited by-同舟云学术

Phosphine-promoted ring-opening of benzisothiazolinate ligands at a nickel(ii) centre: a convenient synthesis of Ni(ii)-thiolate complexes

Published:2019 Issue:17 Volume:48 Page:5520-5522
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Al-Jibori Subhi A.¹²³⁴⁵,Ali Samer Hussein¹²³⁴⁵,Al-Janabi Ahmed S.⁶⁷³⁴⁵^ORCID,Wagner Christoph⁸⁹¹⁰¹¹¹²,Hogarth Graeme¹¹³¹⁴¹⁵^ORCID

Affiliation:

1. Department of Chemistry

2. College of Science

3. University of Tikrit

4. Tikrit

5. Iraq

6. Department of Biochemistry

7. College of Veterinary Medicine

8. Institut für Chemie

9. Martin-Luther-Universität

10. Halle-Wittenberg

11. D-06120 Halle

12. Germany

13. King's College London

14. London SE1 IDB

15. UK

Abstract

Phosphines react with the benzisothiazolinate (bit) paddlewheel dimer, [Ni₂(μ-bit)₄·2H₂O], resulting in sulfur–nitrogen bond scission and a series of unexpected transformations leading to novel Ni(ii) complexes containing 2-cyanophenylthiolate and related thiolate ligands.

Funder

King’s College London

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00953A

Reference14 articles.

1. Metal complexes of saccharin

2. Novel palladium(II) and platinum(II) complexes of biocidal benzisothiazolinone (Bit); X-ray crystal structures of co-crystallised Bit/BitO and cis-Pd(en)(Bit−1H)2·H2O

3. Palladium(II) benzisothiazolinate (bit) complexes with amino-, acetylamino-, heterocyclic and phosphine co-ligands. Crystal structure of [Pd(bit)2(κ2-dppe)]·2EtOH