Activation of fluoride anion as nucleophile in water with data-guided surfactant selection-Reference-Cited by-同舟云学术

Activation of fluoride anion as nucleophile in water with data-guided surfactant selection

Published:2024 Issue:15 Volume:15 Page:5764-5774
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sharma Krishna¹,McCorry Alison¹,Boobier Samuel¹^ORCID,Mottram James¹,Napier Rachel¹,Ashworth Ian W.²^ORCID,Blacker A. John¹^ORCID,Kapur Nikil³,Warriner Stuart L.¹,Wright Megan H.¹^ORCID,Nguyen Bao N.¹^ORCID

Affiliation:

1. School of Chemistry, University of Leeds, Woodhouse Lane, LS2 9JT, UK

2. Chemical Development, Pharmaceutical, Technology and Development Operations, AstraZeneca, Macclesfield, SK10 2NA, UK

3. School of Mechanical Engineering, University of Leeds, Woodhouse Lane, LS2 9JT, UK

Abstract

A principal component surfactant_map was developed for 91 commercially surfactants for use in surfactant-enabled organic reactions in water. The map led to activation of fluoride anion, usually strongly hydrated, as an active nucleophile in water.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06311A

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