Direct C–H bond activation of ethers and successive C–C bond formation with benzene by a bifunctional palladium–titania photocatalyst

Author:

Tyagi Akanksha1234,Matsumoto Tomoya1234,Kato Tatsuhisa12345,Yoshida Hisao12346

Affiliation:

1. Graduate School of Human and Environmental Studies

2. Kyoto University

3. Kyoto 606-8501

4. Japan

5. Institute for Liberal Arts and Sciences

6. Elements Strategy Initiative for Catalysts and Batteries (ESICB)

Abstract

Palladium-loaded titania bifunctional photocatalysts promoted a simple reaction between benzene and ethers to yield alpha-arylated ethers with high selectivity without consuming any additional chemicals or solvents under mild conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference30 articles.

1. C–H activation

2. C-H Bond Functionalization in Complex Organic Synthesis

3. Handbook of C–H transformations, ed. G. Diker, Wiley-VCH, Weinheim, Germany, 2005

4. Understanding and exploiting C–H bond activation

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