A comparative analysis of hydrosilative amide reduction catalyzed by first-row transition metal (Mn, Fe, Co, and Ni) N-phosphinoamidinate complexes
Author:
Affiliation:
1. Department of Chemistry
2. Dalhousie University
3. Halifax
4. Canada
5. X-Ray Crystallography Laboratory
6. University of Alberta
7. Edmonton
8. Research and Technology
9. Chevron Phillips Chemical Company LP
10. Kingwood
11. USA
Abstract
Screening reveals (PN)Ni(x) pre-catalysts to be effective for the hydrosilative reduction of amides under mild conditions.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04221G
Reference40 articles.
1. S. A. Lawrence , Amines: Synthesis, Properties and Applications , Cambridge University Press , Cambridge , 2006
2. Large-Scale Carbonyl Reductions in the Pharmaceutical Industry
3. Recent Advances in Amide Reductions
4. Tetramethyldisiloxane: A Practical Organosilane Reducing Agent
5. Amine synthesis via transition metal homogeneous catalysed hydrosilylation
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