Formation of an imidazoliumyl-substituted [(LC)4P4]4+ tetracation and transition metal mediated fragmentation and insertion reaction (LC = NHC)-Reference-Cited by-同舟云学术

Formation of an imidazoliumyl-substituted [(LC)4P4]4+ tetracation and transition metal mediated fragmentation and insertion reaction (LC = NHC)

Published:2019 Issue:28 Volume:10 Page:6868-6875
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Schwedtmann Kai¹²³⁴⁵,Haberstroh Jan¹²³⁴⁵,Roediger Sven¹²³⁴⁵,Bauzá Antonio⁶⁷⁸⁹^ORCID,Frontera Antonio⁶⁷⁸⁹^ORCID,Hennersdorf Felix¹²³⁴⁵^ORCID,Weigand Jan J.¹²³⁴⁵^ORCID

Affiliation:

1. Faculty of Chemistry and Food Chemistry

2. TU Dresden

3. Chair of Inorganic Molecular Chemistry

4. 01062 Dresden

5. Germany

6. Department of Chemistry

7. Universitat de Illes Balears

8. 07122 Palma de Mallorca

9. Spain

Abstract

Tetracationic cyclo-tetraphosphane [(L_C)₄P₄]⁴⁺ as triflate salt (L_C = 4,5-dimethyl-1,3-diisopropyl-imidazol-2-yl) is obtained from the reduction of [L_CPCl₂]⁺ with 1,4-bis(trimethylsilyl)-1,4-dihydropyrazine and represents the first salt of the cationic cyclo-phosphane series with the general formula [L_nP_n]ⁿ⁺.

Funder

Deutsche Forschungsgemeinschaft

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01701A

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