How to extract adsorption energies, adsorbate–adsorbate interaction parameters and saturation coverages from temperature programmed desorption experiments

Author:

Vijay Sudarshan1ORCID,Kristoffersen Henrik H.1ORCID,Katayama Yu23ORCID,Shao-Horn Yang245ORCID,Chorkendorff Ib6ORCID,Seger Brian6ORCID,Chan Karen1ORCID

Affiliation:

1. CatTheory, Department of Physics, Technical University of Denmark, 2800 Kgs, Lyngby, Denmark

2. Research Laboratory of Electronics, Massachusetts Institute of Technology, Cambridge, MA 02139, USA

3. Department of Applied Chemistry, Graduate School of Sciences and Technology for Innovation, Yamaguchi University, Tokiwadai, Ube, 755-8611, Japan

4. Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA

5. Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA

6. SurfCat, Department of Physics, Technical University of Denmark, 2800 Kgs, Lyngby, Denmark

Abstract

We present a scheme to extract the adsorption energy, adsorbate interaction parameters and the saturation coverage from temperature programmed desorption (TPD) experiments.

Funder

Japan Society for the Promotion of Science

Horizon 2020 Framework Programme

Villum Fonden

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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5. T.Bligaard , R. M.Bullock , C. T.Campbell , J. G.Chen , B. C.Gates , R. J.Gorte , et al. , Toward Benchmarking in Catalysis Science: Best Practices, Challenges, and Opportunities , ACS Catalysis, 2016 , vol. 6, pp. 2590–2602 . Available from: https://pubs.acs.org/sharingguidelines

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