Annulated boron substituted N-heterocyclic carbenes: theoretical prediction of highly electrophilic carbenes-Reference-Cited by-同舟云学术

Annulated boron substituted N-heterocyclic carbenes: theoretical prediction of highly electrophilic carbenes

Published:2015 Issue:42 Volume:44 Page:18656-18664
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bharadwaz Priyam¹²³⁴,Borthakur Bitupon¹²³⁴,Phukan Ashwini K.¹²³⁴

Affiliation:

1. Department of Chemical Sciences

2. Tezpur University

3. Napaam 784028

4. India

Abstract

Annulated boron substituted N-heterocyclic carbenes are found to have significantly enhanced π-accepting ability which is further corroborated by ³¹P NMR shift calculations of the phosphinidene adducts of these carbenes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT03501E

Reference55 articles.

1. A stable crystalline carbene

2. Electronic stabilization of nucleophilic carbenes

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4. Constructing a Stable Carbene with a Novel Topology and Electronic Framework

5. 2,3-Dihydroimidazol-2-ylidenes and their main group element chemistry

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