Organocatalyzed coupling of carbon dioxide with epoxides for the synthesis of cyclic carbonates: catalyst design and mechanistic studies
Author:
Affiliation:
1. Center for Education and Research on Macromolecules (CERM)
2. CESAM Research Unit
3. Université de Liège
4. Belgium
5. Institut des Sciences Moléculaires
6. UMR 5255 CNRS Université Bordeaux
7. F-33405 Talence Cedex
8. France
Abstract
The coupling of carbon dioxide (CO2) with epoxides with the formation of cyclic carbonates is a highly attractive 100% atom economic reaction. It represents a greener and safer alternative to the conventional synthesis of cyclic carbonates from diols and toxic phosgene.
Funder
Fonds De La Recherche Scientifique - FNRS
Federaal Wetenschapsbeleid
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY00438A
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