A reaction of [2,6-(tBu2PO)2C6H3]NiSCH2Ph with BH3·THF: borane mediated C–S bond cleavage
Author:
Affiliation:
1. School of Chemistry and Chemical Engineering
2. Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials
3. Henan Normal University
4. Xinxiang
5. China
Abstract
C–S bond cleavage of the thiolato ligand of [2,6-(tBu2PO)2C6H3]NiSCH2Ph mediated by BH3 as a suitable model for the transition metal catalyzed C–S bond activation of mercaptans.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04883A
Reference68 articles.
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3. The Liebeskind-Srogl CC Cross-Coupling Reaction
4. Organosulfur Compounds: Electrophilic Reagents in Transition-Metal-Catalyzed Carbon-Carbon Bond-Forming Reactions
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