The effect of a highly twisted CC double bond on the electronic structures of 9,9′-bifluorenylidene derivatives in the ground and excited states

Author:

Takai Atsuro1234ORCID,Freas Dylan J.1234,Suzuki Toshikane12345,Sugimoto Manabu6784,Labuta Jan9234,Haruki Rie101112134,Kumai Reiji101112134,Adachi Shin-ichi101112134,Sakai Hayato141516174,Hasobe Taku141516174,Matsushita Yoshitaka1234,Takeuchi Masayuki12345

Affiliation:

1. Molecular Design and Function Group

2. National Institute for Materials Science (NIMS)

3. Tsukuba

4. Japan

5. Department of Materials Science and Engineering

6. Faculty of Advanced Science and Technology

7. Kumamoto University

8. Kumamoto 860-8555

9. International Center for Materials Nanoarchitectonics (MANA)

10. Photon Factory

11. Institute of Materials Structure Science

12. High Energy Accelerator Research Organization (KEK)

13. Tsukuba 305-0801

14. Department of Chemistry

15. Faculty of Science and Technology

16. Keio University

17. Yokohama

Abstract

A highly twisted CC double bond elicits changes in the physicochemical properties of π-systems.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference36 articles.

1. Carbon-Rich Compounds: From Molecules to Materials, ed. M. M. Haley and R. R. Tykwinski, Wiley-VCH, Weinheim, Germany, 2006

2. Polyarenes II, ed. J. S. Siegel and Y. T. Wu, Springer International Publishing, Cham, Switzerland, 2014

3. C. F. Chen and Y.Shen, Helicene Chemistry: From Synthesis to Applications, Springer-Verlag GmbH, Berlin, Heidelberg, Germany, 2016

4. Thermochromism.

5. Photochromism and thermochromism through partial torsion about an essential double bond. Structure of the B colored isomers of bianthrones

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