Different hybridized oxygen atoms controlled chemoselective formation of oxocarbenium ions: synthesis of chiral heterocyclic compounds
Author:
Affiliation:
1. Key Laboratory of Marine Drugs
2. Chinese Ministry of Education
3. School of Medicine and Pharmacy
4. Ocean University of China
5. Qingdao 266003
Abstract
The chemoselective formation of oxocarbenium ions was realized by the chemoselective protonation of different hybridized oxygen atoms.
Funder
Qingdao National Laboratory for Marine Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB01743C
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1. Mechanism of Cyclization of Pyridine Nucleotides by Bovine Spleen NAD+ Glycohydrolase
2. An Efficient Formal Synthesis of (−)-Clavosolide A Featuring a “Mismatched” Stereoselective Oxocarbenium Reduction
3. Formal Synthesis of (−)-Neopeltolide Featuring a Highly Stereoselective Oxocarbenium Formation/Reduction Sequence
4. Enantioselective Addition of Boronates to Chromene Acetals Catalyzed by a Chiral Brønsted Acid/Lewis Acid System
5. Enantioselective Thiourea-Catalyzed Additions to Oxocarbenium Ions
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