Transformation of lignin model compounds to N-substituted aromatics via Beckmann rearrangement-Reference-Cited by-同舟云学术

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Transformation of lignin model compounds to N-substituted aromatics via Beckmann rearrangement

Published:2018 Issue:14 Volume:20 Page:3318-3326
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Wang Yinling¹²³⁴⁵,Du Yiman¹²³⁴⁵,He Jianghua¹²³⁴⁵,Zhang Yuetao¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Supramolecular Structure and Materials

2. College of Chemistry

3. Jilin University

4. Changchun

5. China

Abstract

Here we present the highly effective cleavage of C–C bonds in lignin model compounds for the production of N-substituted aromatics in up to 96% total yield, including benzonitriles and amides, via oxime formation followed by Beckmann rearrangement (BR).

Funder

National Natural Science Foundation of China

Jilin University

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/GC/C8GC00920A

Reference96 articles.

1. Lignin Valorization: Improving Lignin Processing in the Biorefinery

2. Lignin up for break-down

3. Lignin depolymerisation strategies: towards valuable chemicals and fuels

4. The Catalytic Valorization of Lignin for the Production of Renewable Chemicals

5. Catalytic Transformation of Lignin for the Production of Chemicals and Fuels

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1. Photocatalytic, Oxidative Cleavage of C−C Bond in Lignin Models and Native Lignin;Chemistry – A European Journal;2024-03-11

2. Production of Oximes Directly from Sustainable Lignocellulose‐Derived Aldehydes and Ammonia over HTS‐1 Catalyst;ChemSusChem;2023-11-17

3. Catalytic Strategies and Mechanism Analysis Orbiting the Center of Critical Intermediates in Lignin Depolymerization;Chemical Reviews;2023-04-06

4. Molecular mechanism of the transformation of oxidized lignin to N-substituted aromatics;Organic & Biomolecular Chemistry;2023

5. Successive Cleavage and Reconstruction of Lignin β‐O‐4 Models and Polymer to Access Quinoxalines;ChemSusChem;2022-09-23

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